Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester

نویسندگان

  • Guo-Bin Liu
  • Hong-Yun Zhao
چکیده

Ru(3)(CO)(12)/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru(3)(CO)(12) and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 degrees C in good and high yields.

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عنوان ژورنال:
  • Beilstein Journal of Organic Chemistry

دوره 4  شماره 

صفحات  -

تاریخ انتشار 2008